How deep down the rabbit hole do we want to go?
Dear Dave,
I have to admit I've never looked at nickel-silver rail oxidisation at a microscopic level like some of our members here onlist, (shout out to LK&O Alan ). I guess I feel like a science student at the start of an exercise. We have observable reproducible symtoms, which have been "in the field" tested over decades. We also have a number of hypothesis which could explain the symtoms and effects.
Without the actual microscopic images to confirm/deny the theory, my personal suspicion is:
- As a dry treatment, graphite is unlikely to be able to form a perfectly-continuous air-tight oxygen barrier
(I can't blow air-bubbles thru a stream/sheet of graphite powder,
nor can I get a vacuum-seal on a sheet of glass which has a load of graphite dust covering it's surface)
- However, we can prove (thru naked-eye observation of both operation, wheelsets, and rail surface) that graphite applied with a single swipe from a 2B "woodless pencil" on one section of track can easily be transmitted to the wheelset treads, and spread around/across the layout via train movement.
(Bonus points: a graphite-coated rail looks less "gleaming yellowish" and more "dull grey silver", which tends to be less visually intrusive and more in-keeping with weathered rail aesthetic).
- If we accept that electricity can track accross a layer of graphite, then the idea that the graphite is acting as a "conductive surface" accross the top of (miniscule, esp immediately after a decent PECO trackblock cleaning?) sections of oxidisation, and creating conductive-layer "jumpers" between (varying size) areas of non-oxidised conductive surface seems viable, and gels with observed behaviour.
- Whether (2B?) graphite is more or less physically/mechanically hard-wearing than surface-based oxygen contamination/oxidisation on Nickel-Sliver rail is unknown to me at this time.
However, we do know that graphite on rail surfaces can coat passing wheel treads, and said coated wheeltreads can transfer/deposit graphite on rail.
Whether that means that the oft-stated "run trains more often = less oxidisation issues" is due to the oxidiation being polished-away with the passing friction of the wheels while the graphite remains,
(IE graphite is harder than NS-surface-borne oxide),
or whether the effective "continual re-distribution/re-application of graphite by passing graphite-coated wheels", simply masks/over-coats any developing oxidisation occurances with more "layer of conductive material" in realtime
(compounding/related issue as above, does graphite exclude contact between Oxygen and Nickel-Silver?
If not, does oxide which forms on top of a graphite layer "harder-wearing" than oxide that forms directly on a clean NS surface?
Oh dear, why do I feel like we've taken the Red Pill???
is again also up-for-analysis...
Whatever the case, at the risk of sounding like a cracked record, it's been proven for my situation and layouts, and the layouts of many modellers I know of accross Australia (from Sydney in the East to Perth in the West, and from Brisbane in the north to Tasmania in the South, so no lack of varying temperatures/humidities/proximity-to-sea/saltwater/average-airborne-dust/layout-construction conditions under test) for some decades now.
As such, personally, I'm not actually greatly concerned about the microscopic "how it works",
although if someone wants to visit Sydney Aust to do the analysis,
I'd be more than happy to provide verifiably "clean rail" and "graphite-treated" test subjects...
Happy Modelling,
Aim to Improve,
Prof Klyzlr
PS linking back to some of the earlier posts, I wonder what the comparative adhesion/friction values are of
- raw NS rail <> NS wheel
- graphited NS rail <> NS wheel
- CRC'd NS rail <> NS wheel
- Railzip'd NS rail <> NS wheel
- No-Ox'd NS rail <> NS wheel